Butylzinc bromide solution

ALDRICH/497746 - 0.5 M in THF

CAS Number: 92273-73-9
Empirical Formula (Hill Notation): C₄H₉BrZn
Molecular Weight: 202.41
MDL Number: MFCD00671997
Linear Formula: CH₃(CH₂)₃ZnBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-497746-50ML	50 mL	$355.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	0.5 M in THF
density	0.958 g/mL at 25 °C
InChI	1S/C4H9.BrH.Zn/c1-3-4-2;;/h1,3-4H2,2H3;1H;/q;;+1/p-1
InChI key	HMBGXQKLGHIDMN-UHFFFAOYSA-M
Quality Level	100
SMILES string	CCCC[Zn]Br
storage temp.	2-8°C

Application:	Butylzinc bromide is an organozinc compound, which can be used as a reagent: • In palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bond by reacting with organic halides or triflates. • To prepare n-butylanisole by treating with 4-bromoanisole in the presence of a tetraphosphine ligand and a palladium catalyst.
Legal Information:	Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.
Packaging:	50 mL in Sure/Seal™

Symbol	GHS02,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H302 - H319 - H335 - H351
Precautionary statements	P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
Hazard Codes	F,Xn
Risk Statements	11-19-36/37-40
Safety Statements	16-26-36/37
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	1.4 °F - closed cup
Flash Point(C)	-17 °C - closed cup
Supplemental Hazard Statements	EUH019

Density	0.958 g/mL at 25 °C
Storage Temp.	2-8°C
UNSPSC	12352103

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