Cyclohexylzinc bromide solution

ALDRICH/498033 - 0.5 M in THF

Synonym: Cyclohexylzinc(II)bromide

CAS Number: 7565-57-3
Empirical Formula (Hill Notation): C₆H₁₁BrZn
Molecular Weight: 228.45
MDL Number: MFCD00671993
Linear Formula: C₆H₁₁ZnBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-498033-50ML	50 mL	$296.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	0.5 M in THF
density	0.963 g/mL at 25 °C
InChI	1S/C6H11.BrH.Zn/c1-2-4-6-5-3-1;;/h1H,2-6H2;1H;/q;;+1/p-1
InChI key	XHGMTEIVIUFIPO-UHFFFAOYSA-M
SMILES string	Br[Zn]C1CCCCC1
storage temp.	2-8°C

Application:	Cyclohexylzinc bromide is an organozinc reagent, generally used in Negishi coupling. Examples include the cross-coupling of alkylzinc halides with aryl/heteroaryl halides using Pd-PEPPSI-IPent and nickel-catalyzed synthesis of 4-substituted coumarins. It can react with the SO₂ surrogate, 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) to afford zinc sulfinate salts which can be alkylated to synthesize various useful sulfones.
Legal Information:	Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.
Packaging:	50 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H302 - H314 - H335 - H336 - H351
Precautionary statements	P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-14-19-34-37-40
Safety Statements	16-26-36/37/39-45
RIDADR	UN 2056 3 / PGII
WGK Germany	WGK 3
Flash Point(F)	3.0 °F - closed cup
Flash Point(C)	-16.1 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

Density	0.963 g/mL at 25 °C
Storage Temp.	2-8°C
UNSPSC	12352103

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