Cyclopentylzinc bromide solution

ALDRICH/498041 - 0.5 M in THF

Synonym: Bromo(cyclopentyl)zinc; Bromocyclopentylzinc

CAS Number: 171860-68-7
Empirical Formula (Hill Notation): C₅H₉BrZn
Molecular Weight: 214.42
MDL Number: MFCD00671991
Linear Formula: C₅H₉ZnBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-498041-50ML	50 mL	$367.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	0.5 M in THF
density	0.955 g/mL at 25 °C
InChI	1S/C5H9.BrH.Zn/c1-2-4-5-3-1;;/h1H,2-5H2;1H;/q;;+1/p-1
InChI key	GOPYCBPMCCJYSN-UHFFFAOYSA-M
Quality Level	100
SMILES string	Br[Zn]C1CCCC1
storage temp.	2-8°C

Application:	Cyclopentylzinc bromide is an organozinc reagent that can be used in: • The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis. • Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst. • The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.
Legal Information:	Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.
Packaging:	50 mL in Sure/Seal™

Symbol	GHS02,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H261 - H302 - H315 - H319 - H335 - H351
Precautionary statements	P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
Hazard Codes	F,Xn
Risk Statements	11-14-19-36/37-40
Safety Statements	16-26-36/37
RIDADR	UN 3399BC 4.3(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	1.4 °F - closed cup
Flash Point(C)	-17 °C - closed cup
Supplemental Hazard Statements	EUH019

Density	0.955 g/mL at 25 °C
Storage Temp.	2-8°C
UNSPSC	12352103

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