1-Chloro-N,N,2-trimethyl-1-propenylamine
ALDRICH/498270 - 96%
Synonym: Ghosez′s reagent
CAS Number: 26189-59-3
Empirical Formula (Hill Notation): C6H12ClN
Molecular Weight: 133.62
MDL Number: MFCD00800562
Linear Formula: (CH3)2C=C(Cl)N(CH3)2
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 498270-50ML
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 498270-5ML
| assay | 96% |
| bp | 129-130 °C (lit.) |
| density | 1.01 g/mL at 25 °C (lit.) |
| InChI | 1S/C6H12ClN/c1-5(2)6(7)8( |
| InChI key | GQIRIWDEZSKOCN-UHFFFAOYSA |
| refractive index | n |
| SMILES string | CN(C)C(Cl)=C(C)C |
| storage temp. | 2-8°C |
| Application: | 1-Chloro-N,N,2-trimethyl-1-propenylam developed by Ghosez, that enables the conversion of carboxylic acids into the corresponding chlorides under strictly neutral conditions. This method was successfully used in the total synthesis of caloporoside, roseophilin, (-)-enniatin B, (±)-epimeloscine and (±)-meloscine. |
| Packaging: | 5, 50, 250 mL in glass bottle |
| Symbol |   GHS02,GHS05 |
| Signal word | Danger |
| Hazard statements | H226 - H314 |
| Precautionary statements | P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338 |
| Hazard Codes | C |
| Risk Statements | 10-34 |
| Safety Statements | 16-26-36/37/39-45 |
| RIDADR | UN 2734PSN1 3(8) / PGI |
| WGK Germany | WGK 3 |
| Flash Point(F) | 80.0 °F - closed cup |
| Flash Point(C) | 26.67 °C - closed cup |
| Purity | 96% |
| bp | 129-130 °C (lit.) |
| Density | 1.01 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352302 |