4-Ethoxy-4-oxobutylzinc bromide solution

ALDRICH/498491 - 0.5 M in THF

Synonym: (4-Ethoxy-4-oxobutyl)zinc(II) bromide; Bromo[4-ethoxy-4-(oxo-κO)butyl-κC]zinc

CAS Number: 131379-39-0
Empirical Formula (Hill Notation): C₆H₁₁BrO₂Zn
Molecular Weight: 260.44
MDL Number: MFCD00671977
Linear Formula: C₂H₅O₂C(CH₂)₃ZnBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-498491-50ML	50 mL	$318.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	0.5 M in THF
density	0.976 g/mL at 25 °C
functional group	ester
InChI	1S/C6H11O2.BrH.Zn/c1-3-5-6(7)8-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1
InChI key	QRIVZBPOANGBFR-UHFFFAOYSA-M
Quality Level	100
SMILES string	CCOC(=O)CCC[Zn]Br
storage temp.	2-8°C

Application:	4-Ethoxy-4-oxobutylzinc bromide can be used: • As an intermediate in one of the key synthetic steps for the preparation of acrylic acid derivatives as EP3 receptor antagonists. • As an intermediate in the final step of the total synthesis of a natural product mucosin. • As a substrate in the synthesis of multi-substituted haloalkenes by reacting with 1-haloalkenes via Negishi cross-coupling reaction.
Legal Information:	Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.
Packaging:	50 mL in Sure/Seal™

Symbol	GHS07,GHS08
Signal word	Warning
Hazard statements	H319 - H335 - H351
Precautionary statements	P261 - P281 - P305 + P351 + P338
Hazard Codes	Xn
Risk Statements	19-36/37-40
Safety Statements	26-36/37
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	-6.2 °F - (THF)
Flash Point(C)	-21.2 °C - (THF)
Supplemental Hazard Statements	EUH019

Density	0.976 g/mL at 25 °C
Storage Temp.	2-8°C
UNSPSC	12352103

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