3-Ethoxy-3-oxopropylzinc bromide solution

ALDRICH/498521 - 0.5 M in THF

Synonym: (2-Ethoxycarbonylethyl)zinc bromide; (3-Ethoxy-3-oxopropyl)zinc(II)bromide; 3-Ethoxy-3-oxopropylzinc bromide

CAS Number: 193065-68-8
Empirical Formula (Hill Notation): C₅H₉BrO₂Zn
Molecular Weight: 246.42
MDL Number: MFCD00671976
Linear Formula: C₂H₅O₂CCH₂CH₂ZnBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-498521-50ML	50 mL	$304.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	0.5 M in THF
density	0.972 g/mL at 25 °C
functional group	ester
InChI	1S/C5H9O2.BrH.Zn/c1-3-5(6)7-4-2;;/h1,3-4H2,2H3;1H;/q;;+1/p-1
InChI key	XLKAROLEWCMBDC-UHFFFAOYSA-M
Quality Level	100
SMILES string	CCOC(=O)CC[Zn]Br
storage temp.	2-8°C

Application:	3-Ethoxy-3-oxopropylzinc bromide is a reagent used to insert ethyl propanoate group to the substrate. It can be used in: • Synthesis of γ-keto esters from aryl chlorides. • Synthesis of sulfones from 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO) and alkyl halides. • Negishi cross-couplings with aryl vinyl phosphates to synthesize 1,1-disubstituted alkenes.
Legal Information:	Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.
Packaging:	50 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H302 - H314 - H335 - H351
Precautionary statements	P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
Hazard Codes	F,C
Risk Statements	11-19-34-37-40
Safety Statements	9-16-26-33-36/37/39-45
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	1.4 °F - closed cup
Flash Point(C)	-17.0 °C - closed cup
Supplemental Hazard Statements	EUH019

Density	0.972 g/mL at 25 °C
Storage Temp.	2-8°C
UNSPSC	12352103

To Order From a Quote