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(2-Naphthylmethyl)zinc bromide solution

ALDRICH/499021 - 0.5 M in THF

CAS Number: 152329-44-7
Empirical Formula (Hill Notation): C11H9BrZn
Molecular Weight: 286.48
MDL Number: MFCD01311438
Linear Formula: C10H7CH2ZnBr
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-499021-50ML 50 mL
 $285.00
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concentration 0.5 M in THF
density 0.978 g/mL at 25 °C
InChI 1S/C11H9.BrH.Zn/c1-9-6-7-10-4-2-3-5-11(10)8-9;;/h2-8H,1H2;1H;/q;;+1/p-1
InChI key IKDINBHMSAHXCA-UHFFFAOYSA-M
Quality Level 100 
SMILES string Br[Zn]Cc1ccc2ccccc2c1
storage temp. 2-8°C
Application: (2-Naphthylmethyl)zinc bromide can be used as a reagent for the synthesis of:
•  4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile from 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile using Pd catalyst.
•  (E)-stilbene, (2,2′-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]) from 1,4-benzenedicarboxaldehyde in the presence of Pd catalyst and a silylating agent.
General description: (2-Naphthylmethyl)zinc bromide is an organozinc halide, which is typically used as a reagent in Negishi cross-coupling reactions. In this process, the organozinc halide reacts with organic halides or triflates to form a carbon-carbon bond in the presence of a Pd catalyst.
Legal Information: Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Packaging: 50 mL in Sure/Seal™
Density 0.978 g/mL at 25 °C
Storage Temp. 2-8°C
UNSPSC 12352103

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