Phenethylzinc bromide solution

ALDRICH/499307 - 0.5 M in THF

CAS Number: 308796-14-7
Empirical Formula (Hill Notation): C₈H₉BrZn
Molecular Weight: 250.45
MDL Number: MFCD01311437
Linear Formula: C₆H₅CH₂CH₂ZnBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-499307-50ML	50 mL	$370.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

bp	65 °C
concentration	0.5 M in THF
density	0.965 g/mL at 25 °C
InChI	1S/C8H9.BrH.Zn/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q;;+1/p-1
InChI key	SEXSOTWHLBYVNF-UHFFFAOYSA-M
SMILES string	Br[Zn]CCc1ccccc1
storage temp.	2-8°C

Application:	Phenethylzinc bromide can be used as a reagent: • In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation. • To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction. • To synthesize benzyl substituted thienopyrimidine derivatives.
Legal Information:	Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.
Packaging:	50 mL in Sure/Seal™

Symbol	GHS02,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H319 - H335 - H336 - H351
Precautionary statements	P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313
Hazard Codes	F,Xn
Risk Statements	11-14-19-36/37-40
Safety Statements	16-26-36/37
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	1.4 °F - closed cup
Flash Point(C)	-17 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

bp	65 °C
Density	0.965 g/mL at 25 °C
Storage Temp.	2-8°C
UNSPSC	12352103

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