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(S)-(−)-2-Methyl-2-propanesulfinamide

ALDRICH/513210 - 97%

Synonym: (S)-(-)-tert-Butanesulfinamide; (S)-(-)-tert-Butyl sulfinamide; (S)-2-Methyl-2-propanesulfinamide; (S)-tert-Butanesulfinamide; (S)-tert-Butylsulfinamide

CAS Number: 343338-28-3
Empirical Formula (Hill Notation): C4H11NOS
Molecular Weight: 121.20
MDL Number: MFCD05861480
Linear Formula: (CH3)3CS(O)NH2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-513210-1G 1 g
 $84.70
1/EA		 Add To Favorites
45-513210-5G 5 g
 $228.00
1/EA		 Add To Favorites
45-513210-25G 25 g
 $737.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 513210-25G

 

assay 97%
InChI 1S/C4H11NOS/c1-4(2,3)7(5)6/h5H2,1-3H3/t7-/m0/s1
InChI key CESUXLKAADQNTB-ZETCQYMHSA-N
mp 97-101 °C (lit.)
optical activity [α]20/D −4.5°, c = 1 in chloroform
Quality Level 100 
SMILES string CC(C)(C)S(N)=O
storage temp. 2-8°C
Application: (S)-(-)-2-Methyl-2-propanesulfinamide may be used to develop benzofuran-based farnesyltransferase inhibitors as anti-cancer agents. It may also be used to prepare (20E)-N-[t-butyl-(S)-sulfinyl]-3β-(t-butyldimethylsilyloxy)-pregn-5-en-20-imine, an intermediate for the preparation of androgen receptor antagonists.
Application: Ellman′s Sulfinamides 
Application: Can be readily transformed into P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins.
Application: Chiral auxiliary used in an asymmetric preparation of trifluoroethylamines by conversion of trifluoroacetaldehyde to a chiral imine followed by treatment with an aryl lithium and acidic methanolysis.
Application: Useful reagent for synthesizing chiral amines.
Packaging: 1, 5, 25 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
mp 97-101 °C (lit.)
Storage Temp. 2-8°C
UNSPSC 12352111

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