Cesium hydroxide monohydrate
ALDRICH/516988 - 99.95% trace metals basis
Synonym: 2-Aminoethyl 2-methylacrylate hydrochloride; 2-Aminoethyl methacrylate hydrochloride; Methacrylic acid, 2-aminoethyl ester, hydrochloride
CAS Number: 35103-79-8
Empirical Formula (Hill Notation): HCsO · H2O
Molecular Weight: 167.93
EC Number: 244-344-1
MDL Number: MFCD00010964
Linear Formula: HCsO · H2O
Product Type: Chemical
assay | 99.95% trace metals basis |
density | 3.68 g/mL at 25 °C (lit.) |
form | powder |
impurities | ≤550.0 ppm Trace Metal Analysis |
InChI | 1S/Cs.H2O/h;1H2/q+1;/p-1 |
InChI key | HUCVOHYBFXVBRW-UHFFFAOYSA |
mp | 272 °C (lit.) |
SMILES string | [Cs+].[O-][H].[H]O[H] |
Application: | Cesium hydroxide monohydrate can be used as a catalyst in the synthesis of:• O-allenes and N-allenes via isomerization of terminal alkynes. This method allows the efficient synthesis of allenes in high yields under mild conditions with wide functional group tolerance. • Unsymmetrical bis-allyl ethers consist of an E-allylic unit and a terminal allylic unit via dimerization of Baylis-Hillman adducts. Cesium hydroxide monohydrate can also be used as an initiator for the heterogeneous ring-opening polymerization of monosubstituted oxiranes. |
General description: | Cesium hydroxidemonohydrate is commonly used as a catalyst in many organic transformations andas an initiator in polymerization reactions. |
Packaging: | 5, 25 g in poly bottle |
Symbol | GHS05,GHS07 |
Signal word | Danger |
Hazard statements | H302 - H314 |
Precautionary statements | P260 - P270 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 |
Hazard Codes | C |
Risk Statements | 22-35 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 2682 8 / PGII |
WGK Germany | WGK 1 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 99.95% trace metals basis |
mp | 272 °C (lit.) |
Density | 3.68 g/mL at 25 °C (lit.) |
UNSPSC | 12352302 |