Shi Epoxidation Diketal Catalyst
ALDRICH/520160 - 98%
Synonym: 1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose
CAS Number: 18422-53-2
Empirical Formula (Hill Notation): C12H18O6
Molecular Weight: 258.27
MDL Number: MFCD11865369
Linear Formula: C12H18O6
Product Type: Chemical
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.
| assay | 98% |
| greener alternative category |  , Aligned |
| greener alternative product characteristics | Catalysis Learn more about the Principles of Green Chemistry . |
| InChI | 1S/C12H18O6/c1-10(2)15-6- |
| InChI key | IVWWFWFVSWOTLP-RWYTXXIDSA |
| mp | 102-104 °C (lit.) |
| optical activity | [α]20/D −120.9°, c = 1 in chloroform |
| SMILES string | CC1(C)O[C@@H]2CO[C@]3(COC |
| sustainability | Greener Alternative Product |
| Application: | Highly selective and active organocatalyst for the asymmetric epoxidation of alkenes with hydrogen peroxide. Green epoxidation catalyst of choice according to Glaxo-Smith-Kline's reagent guide. An Efficient Catalytic Asymmetric Epoxidation Method  Use of an Iridium-Catalyzed Redox-Neutral Alcohol-Amine Coupling on Kilogram Scale for the Synthesis of a GlyT1 Inhibitor |
| Application: | This organocatalyst is able to epoxidize trans alkenes and certain cis alkenes with good to excellent yields and selectivities. |
| General description: | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. |
| Packaging: | 5 g in glass bottle |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 98% |
| mp | 102-104 °C (lit.) |
| UNSPSC | 12352005 |