Palladium(II) chloride
ALDRICH/520659 - ≥99.9%
Synonym: Dichloropalladium; Palladium dichloride; Palladous chloride
CAS Number: 7647-10-1
Empirical Formula (Hill Notation): Cl2Pd
Molecular Weight: 177.33
EC Number: 231-596-2
MDL Number: MFCD00003558
Linear Formula: Cl2Pd
Product Type: Chemical
PdCl2
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 520659-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 520659-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 520659-25G
| assay | ≥99.9% |
| composition | Pd, 59-60% |
| density | 4 g/mL at 25 °C (lit.) |
| InChI | 1S/2ClH.Pd/h2*1H;/q;;+2/p |
| InChI key | PIBWKRNGBLPSSY-UHFFFAOYSA |
| mp | 678-680 °C (lit.) |
| Quality Level | 100  |
| reaction suitability | core: palladium |
| reaction type: Buchwald-Hartwig Cross Coupling Reaction | |
| reaction type: Heck Reaction | |
| reaction type: Hiyama Coupling | |
| reaction type: Negishi Coupling | |
| reaction type: Sonogashira Coupling | |
| reaction type: Stille Coupling | |
| reaction type: Suzuki-Miyaura Coupling | |
| reagent type: catalyst | |
| SMILES string | Cl[Pd]Cl |
| Application: | Application Guide for Palladium Catalyzed Cross-Coupling Reactions Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar. |
| Application: | Palladium(II) chloride (PdCl2) was used in the following studies: • As catalyst for the carbonylation of organic tellurides by reaction with carbon monoxide. • As a catalyst along with Cu(II) for the deamination of phenethylamines to phenyl substituted pyrroles. • Together with PEG 300, promoted efficient Suzuki-coupling of aryl chlorides with aryl boronic acids. For small scale and high throughput uses, product is also available as ChemBeads (919853 ) |
| General description: | Palladium(II) chloride (PdCl2) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters. PdCl2 reacts with N,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy Palladium(II) chloride is used as an oxidizing agent and catalyst for the Suzuki-Miyaura and Mizoroki-Heck reactions. |
| Packaging: | 1, 5, 25, 100 g in glass bottle |
| Symbol |    GHS05,GHS07,GHS09 |
| Signal word | Danger |
| Hazard statements | H290 - H302 - H317 - H318 - H410 |
| Precautionary statements | P273 - P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310 |
| Hazard Codes | T |
| Risk Statements | 25-43 |
| Safety Statements | 36/37-45 |
| RIDADR | UN 3288 6.1 / PGIII |
| WGK Germany | WGK 3 |
| Purity | ≥99.9% |
| mp | 678-680 °C (lit.) |
| Density | 4 g/mL at 25 °C (lit.) |
| UNSPSC | 12161600 |