Palladium(II) acetate
ALDRICH/520764 - ≥99.9% trace metals basis
Synonym: Pd(OAc)2; [Pd(OAc)2]3
CAS Number: 3375-31-3
Empirical Formula (Hill Notation): C4H6O4Pd
Molecular Weight: 224.51
EC Number: 222-164-4
MDL Number: MFCD00012453
Linear Formula: Pd(OCOCH3)2
Product Type: Chemical
Pd(OAc)2 catalyst
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 520764-100G.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 520764-1G.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 520764-25G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 520764-1G
| assay | ≥99.9% trace metals basis |
| InChI | 1S/2C2H4O2.Pd/c2*1-2(3)4; |
| InChI key | YJVFFLUZDVXJQI-UHFFFAOYSA |
| mp | 216.3-223.7 °C (dec.) |
| Quality Level | 200  |
| reaction suitability | core: palladium |
| reaction type: Buchwald-Hartwig Cross Coupling Reaction | |
| reaction type: Cross Couplings | |
| reaction type: Heck Reaction | |
| reaction type: Hiyama Coupling | |
| reaction type: Negishi Coupling | |
| reaction type: Sonogashira Coupling | |
| reaction type: Stille Coupling | |
| reaction type: Suzuki-Miyaura Coupling | |
| reagent type: catalyst reaction type: C-H Activation |
|
| SMILES string | CC(O[Pd]OC(C)=O)=O |
| Application: | Application Guide for Palladium Catalyzed Cross-Coupling Reactions |
| Application: | Palladium(II) acetate was employed as a catalyst for the following reactions: • Formation of allylic acetates. (eq. 1) • Hydroselenation of triple bonds. (eq. 2) • Heck arylation of alkenes. (eq. 3) • Cyclocarbonylation. (eq. 4) • Buchwald-Hartwig amination reaction. (eq. 5)  For small scale and high throughput uses, product is also available as ChemBeads (924377 ) |
| General description: | Palladium(II) acetate is a homogenous oxidation catalyst. It participates in the activation of alkenic and aromatic compounds towards oxidative inter- and intramolecular nucleophilic reactions. Crystals of palladium(II) acetate have a trimeric structure, having symmetry D3h. Each of the palladium atoms in the crystals are joined to the other two by double acetate bridges. Microencapsulation of palladium(II) acetate in polyurea affords polyurea-encapsulated palladium(II) acetate. It is a versatile heterogeneous catalyst for various phosphine-free cross-coupling reactions. It participates as catalyst in the Heck coupling reaction of pthalides with different alkenes. |
| Packaging: | 1, 5, 25, 100 g in glass bottle |
| Symbol |    GHS05,GHS07,GHS09 |
| Signal word | Danger |
| Hazard statements | H317 - H318 - H410 |
| Precautionary statements | P261 - P272 - P273 - P280 - P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 41 |
| Safety Statements | 26-39 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 2 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥99.9% trace metals basis |
| mp | 216.3-223.7 °C (dec.) |
| UNSPSC | 12161600 |