Potassium tetrachloroplatinate(II)
ALDRICH/520853 - ≥99.9% trace metals basis
Synonym: Potassium platinum(II) chloride
CAS Number: 10025-99-7
Empirical Formula (Hill Notation): Cl4K2Pt
Molecular Weight: 415.09
EC Number: 233-050-9
MDL Number: MFCD00011378
Linear Formula: K2PtCl4
Product Type: Chemical
assay | ≥99.9% trace metals basis |
composition | Pt, ≥46.2% |
density | 3.38 g/mL at 25 °C (lit.) |
form | powder or crystals |
impurities | ≤1000.0 ppm Trace Metal Analysis |
InChI | 1S/4ClH.2K.Pt/h4*1H;;;/q; |
InChI key | RVRDLMCWUILSAH-UHFFFAOYSA |
SMILES string | [K+].[K+].Cl[Pt--](Cl)(Cl |
Application: | Potassium tetrachloroplatinate(II) can be used:• As a precursor to prepare platinum nanoparticles and mesoporous platinum nanospheres with tunable pore sizes. • As a catalyst for selective methane oxidation through C-H activation. In addition, to synthesize octahedral Pd@Pt1.8Ni nanocrystals with an ultrathin PtNi alloy shell. The nanocrystals exhibited better ORR activity and durability than the commercial Pt/C for fuel cells. • To prepare Pt atomic clusters were synthesized using a one-step carbon-defect-driven electroless deposition method. These catalysts demonstrated low overpotential, high activity for the hydrogen evolution reaction, exceptional stability, and improved utilization efficiency of Pt. The Pt-AC/DG (Atomic Clusters/Defective Graphene) cathode showed excellent hydrogen production activity, remarkable stability, and significantly reduced Pt usage compared to the Pt/C catalyst. • As a starting material to synthesize cyclometalated platinum(II) complexes with long-lived luminescence in solution. |
Features and Benefits: | Reacts with bis(dithiolates) to form metal-bis(dithiolates) with applications in laser Q-switch materials, liquid crystals, optical CD recording media, bar code materials and superconductivity. Reacts with capping polymers to form shape-control colloidal platinum nanoparticles for catalysis and photocatalysts. |
General description: | Potassium tetrachloroplatinate(II) is a crystalline solid that is insoluble in water and soluble in organic solvents. It is widely used in the field of nanomaterial synthesis, catalysis, and energy storage. |
Packaging: | 1, 5, 25 g in glass bottle |
Symbol | GHS05,GHS06,GHS08 |
Signal word | Danger |
Hazard statements | H301 - H315 - H317 - H318 - H334 |
Precautionary statements | P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 + P310 |
Hazard Codes | T |
Risk Statements | 25-38-41-42/43 |
Safety Statements | 22-26-36/37/39-45 |
RIDADR | UN 3288 6.1 / PGIII |
WGK Germany | WGK 1 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | ≥99.9% trace metals basis |
Density | 3.38 g/mL at 25 °C (lit.) |
UNSPSC | 12352302 |