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Cyclopropylmagnesium bromide solution

ALDRICH/526797 - 0.5 M in THF

Synonym: Bromocyclopropylmagnesium

CAS Number: 23719-80-4
Empirical Formula (Hill Notation): C3H5BrMg
Molecular Weight: 145.28
MDL Number: MFCD00672094
Linear Formula: C3H5BrMg
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-526797-100ML 100 mL
 $323.00
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45-526797-800ML 800 mL
 $1990.00
1/EA		 Add To Favorites
25 mL Sure/Seal™ Packaging

 

bp 65 °C
concentration 0.5 M in THF
density 0.968 g/mL at 25 °C
InChI 1S/C3H5.BrH.Mg/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1
InChI key QUPLLJGAJVXXBW-UHFFFAOYSA-M
Quality Level 100 
reaction suitability reaction type: Grignard Reaction
SMILES string Br[Mg]C1CC1
storage temp. 2-8°C
Application: Cyclopropylmagnesium bromide solution has been used in Grignard reaction that finds application as the key step in the preparation of aminopropylindenes, a chemotype of oxidosqualene cyclase (OSC) inhibitors from Grundmann′s ketone. It can react with trimethylborate to form cyclopropylboronic acid, which can undergo Suzuki-type coupling reactions with different aryl, and heteroaryl bromides to form the cyclopropyl adducts.
Packaging: 100, 800 mL in Sure/Seal™
bp 65 °C
Density 0.968 g/mL at 25 °C
Storage Temp. 2-8°C
UNSPSC 12352103

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