(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride

ALDRICH/531979

Synonym: (S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(III) chloride

CAS Number: 307926-51-8
Empirical Formula (Hill Notation): C₃₆H₅₂AlClN₂O₂
Molecular Weight: 607.24
MDL Number: MFCD02684548
Linear Formula: C₃₆H₅₂AlClN₂O₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-531979-1G	1 g	$212.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

InChI	1S/C36H54N2O2.Al.ClH/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;;1H/q;+3;/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1
InChI key	KGVBCKDZFMLRMA-RUIQGICGSA-K
mp	>350 °C (lit.)
SMILES string	CC(C)(C)c1cc2C=N[C@H]3CCCC[C@@H]3N=Cc4cc(cc(c4O[Al](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C

Application:	(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride can be used as a chiral catalyst: • In the preparation of substituted hydroxyalkyl aminooxazole derivatives by reacting isocyanides with aldehydes. • In the cyanation of α,β-unsaturated imides to yield saturated imides.
Legal Information:	Sold under license from Sterling Pharma Solutions Limited.
Packaging:	1 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 + H312 + H332
Precautionary statements	P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312
Hazard Codes	Xn
Risk Statements	20/21/22
Safety Statements	26-36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	>350 °C (lit.)
UNSPSC	12352101

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