2-Amino-6-bromobenzothiazole

ALDRICH/538507 - 97%

CAS Number: 15864-32-1
Empirical Formula (Hill Notation): C₇H₅BrN₂S
Molecular Weight: 229.10
MDL Number: MFCD00152229
Linear Formula: C₇H₅BrN₂S
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-538507-1G	1 g	$29.80 1/EA		Add To Favorites
45-538507-5G	5 g	$50.70 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
form	solid
InChI	1S/C7H5BrN2S/c8-4-1-2-5-6(3-4)11-7(9)10-5/h1-3H,(H2,9,10)
InChI key	VZEBSJIOUMDNLY-UHFFFAOYSA-N
mp	213-217 °C (lit.)
Quality Level	100
SMILES string	Nc1nc2ccc(Br)cc2s1

Application:	2-Amino-6-bromobenzothiazole may be used in the synthesis of the following • 2-amino-6-arylbenzothiazole compounds: • 6-p-tolylbenzo[d]thiazole-2-amine • 6-(4chlorophenyl)benzo[d]thiazole-2-amine • 6-(4-methoxyphenyl)benzo[d]thiazole-2-amine • 6-(3,5-bis(triflouromethyl)phenyl)benzo[d]thiazole-2-amine • 6-phenylbenzo[d]thiazole-2-amine It may be employed as a ligand (L) in the synthesis of organometallic derivatives of Rh(I) [Rh(CO)₂(L)(Cl)].
General description:	Reaction of 4-bromoaniline with acetic acid and potassium thiocynate in solution of bromine in acetic acid yields 2-amino-6-bromobenzothiazole. 2-Amino-6-bromobenzothiazole can also be synthesized from 2-aminobenzothiazole via monobromination with silica-supported quinolinium tribromide.
Packaging:	1, 5, 25 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 - H317 - H319
Precautionary statements	P261 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
Hazard Codes	Xn
Risk Statements	22-36-43
Safety Statements	26-36/37
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	97%
mp	213-217 °C (lit.)
UNSPSC	12352100

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