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(R)-1,4-Dioxaspiro[4.5]decane-2-carboxaldehyde

ALDRICH/543039

Synonym: (R)-2,3-Cyclohexylideneglyceraldehyde; (R)-Cyclohexylideneglyceraldehyde; 2,3-O-Cyclohexylidene-D-glyceraldehyde; O,O-Cyclohexylidene-(R)-glyceraldehyde

CAS Number: 78008-36-3
Empirical Formula (Hill Notation): C9H14O3
Molecular Weight: 170.21
MDL Number: MFCD03093997
Linear Formula: C9H14O3
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-543039-1G 1 g
 $227.00
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density 1.108 g/mL at 25 °C (lit.)
InChI 1S/C9H14O3/c10-6-8-7-11-9(12-8)4-2-1-3-5-9/h6,8H,1-5,7H2/t8-/m0/s1
InChI key FFGZPNNLXMQFMO-QMMMGPOBSA-N
optical activity [α]/D 60±10° in chloroform
refractive index n20/D 1.472 (lit.)
SMILES string O=C[C@H]1COC2(CCCCC2)O1
Application: Reactant for:
• Proline-catalyzed Diels Alder reaction
• Stereodivergent synthesis of carbahexofuranoses employing a Wittig olefination-Claisen rearrangement protocol
• Wittig reactions
• Crotylation reactions
• Asymmetric synthesis of Goniothalesdiol A via stereocontrolled allylation and base-catalyzed oxy-Michael addition
Application: Used as a building block.
Other Notes: Contains varying amounts of polymer
Packaging: 1 g in glass bottle
Density 1.108 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.472 (lit.)
UNSPSC 12352005

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