(R)-1,4-Dioxaspiro[4.5]decane-2-carboxaldehyde

ALDRICH/543039

Synonym: (R)-2,3-Cyclohexylideneglyceraldehyde; (R)-Cyclohexylideneglyceraldehyde; 2,3-O-Cyclohexylidene-D-glyceraldehyde; O,O-Cyclohexylidene-(R)-glyceraldehyde

CAS Number: 78008-36-3
Empirical Formula (Hill Notation): C₉H₁₄O₃
Molecular Weight: 170.21
MDL Number: MFCD03093997
Linear Formula: C₉H₁₄O₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-543039-1G	1 g	$241.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

density	1.108 g/mL at 25 °C (lit.)
functional group	aldehyde
	ether
	ketal
InChI	1S/C9H14O3/c10-6-8-7-11-9(12-8)4-2-1-3-5-9/h6,8H,1-5,7H2/t8-/m0/s1
InChI key	FFGZPNNLXMQFMO-QMMMGPOBSA-N
optical activity	[α]/D 60±10° in chloroform
Quality Level	100
refractive index	n20/D 1.472 (lit.)
SMILES string	O=C[C@H]1COC2(CCCCC2)O1

Application:	Reactant for: • Proline-catalyzed Diels Alder reaction • Stereodivergent synthesis of carbahexofuranoses employing a Wittig olefination-Claisen rearrangement protocol • Wittig reactions • Crotylation reactions • Asymmetric synthesis of Goniothalesdiol A via stereocontrolled allylation and base-catalyzed oxy-Michael addition
Application:	Used as a building block.
Other Notes:	Contains varying amounts of polymer
Packaging:	1 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3

Density	1.108 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.472 (lit.)
UNSPSC	12352005

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