Tris[N,N-bis(trimethylsilyl)amide]samarium(III)

ALDRICH/547980 - 98%

Synonym: 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt; Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium

CAS Number: 35789-01-6
Empirical Formula (Hill Notation): C₁₈H₅₄N₃Si₆Sm
Molecular Weight: 631.51
MDL Number: MFCD03427097
Linear Formula: Sm(N(Si(CH₃)₃)₂)₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-547980-1G	1 g	$199.00 1/EA	Add To Favorites

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Properties
Descriptions
Safety Info.
Basic Data

assay	98%
form	solid
InChI	1S/3C6H18NSi2.Sm/c31-8(2,3)7-9(4,5)6;/h31-6H3;/q3*-1;+3
InChI key	MUFPZLRACJKLCI-UHFFFAOYSA-N
mp	93-106 °C (lit.)
reaction suitability	core: samarium
	reagent type: catalyst
SMILES string	C[Si](C)(C)N([Sm](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

Application:	Reactant for synthesis of: • Heterobimetallic samarium(III) complexes • Binuclear lanthanide complexes Catalyst for: • Coordination polymerization of renewable butyrolactone-based vinyl monomers • Intramolecular hydroamination of non-activated alkenes • Chiral functionalization of isoxazoles • Enantioselective hydroamination / cyclization
Packaging:	1 g in glass bottle

Symbol	GHS02,GHS05
Signal word	Danger
Hazard statements	H228 - H261 - H314
Precautionary statements	P210 - P231 + P232 - P280 - P305 + P351 + P338 - P310 - P422
Hazard Codes	F,C
Risk Statements	11-14/15-34
Safety Statements	7/8-16-26-36/37/39-43-45
RIDADR	UN 3396 4.1(4.3) / PGII
WGK Germany	WGK 3
Flash Point(F)	36.0 °F - closed cup
Flash Point(C)	2.2 °C - closed cup
Supplemental Hazard Statements	EUH014

Purity	98%
mp	93-106 °C (lit.)
UNSPSC	12161600

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