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2-Thienylmagnesium bromide solution

ALDRICH/550442 - 1.0 M in THF

Synonym: (Thiophen-2-yl)magnesium bromide; Bromo-2-thienylmagnesium

CAS Number: 5713-61-1
Empirical Formula (Hill Notation): C4H3BrMgS
Molecular Weight: 187.34
MDL Number: MFCD03094046
Linear Formula: C4H3BrMgS
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-550442-50ML 50 mL
 $336.00
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bp 65 °C
concentration 1.0 M in THF
density 1.011 g/mL at 25 °C
InChI 1S/C4H3S.BrH.Mg/c1-2-4-5-3-1;;/h1-3H;1H;/q;;+1/p-1
InChI key GSHPYJFNTAMRJF-UHFFFAOYSA-M
Quality Level 100 
reaction suitability reaction type: Grignard Reaction
SMILES string Br[Mg]c1cccs1
Application: 2-Thienylmagnesium bromide is a Grignard reagent that can be used as a reactant to synthesize:
•  1-(2-thienyl)-carbinols by condensation reaction with aldehydes. Carbinols are further dehydrated to form 2-thienyl olefins.
•  Thiophene-functionalized polystyrene macromonomer (ThPStM), which is employed as a key intermediate to synthesize polystyrene-graft-polythiophene (PSt-g-PTh) via a combination of atom transfer radical polymerization (ATRP) and Grignard reaction.
•  Thienylene oligomers, which are used as conducting polymers and as potential OLEDs.
Packaging: 50 mL in Sure/Seal™
bp 65 °C
Density 1.011 g/mL at 25 °C
UNSPSC 12352103

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