(1,3-Dioxan-2-ylethyl)magnesium bromide solution
ALDRICH/561657 - 0.5 M in THF
Synonym: 1,3-Dioxane - 2-ethyl- magnesium complex; [2-
CAS Number: 480438-44-6
Empirical Formula (Hill Notation): C6H11BrMgO2
Molecular Weight: 219.36
MDL Number: MFCD00061518
Linear Formula: C6H11BrMgO2
Product Type: Chemical
bp | 65 °C |
concentration | 0.5 M in THF |
density | 0.951 g/mL at 25 °C |
InChI | 1S/C6H11O2.BrH.Mg/c1-2-6- |
InChI key | JYNXRXBIEHSSLR-UHFFFAOYSA |
reaction suitability | reaction type: Grignard Reaction |
SMILES string | Br[Mg]CCC1OCCCO1 |
storage temp. | 2-8°C |
Application: | (1,3-Dioxan-2-ylethyl)mag • In a Grignard addition-acylation method for the preparation of enamides. • To prepare trisubstituted allenes by reacting with propargylic ammonium salts. • In one of the key synthetic steps for the synthesis of febrifugine based antimalarial drugs. |
Legal Information: | Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc. |
Packaging: | 50 mL in Sure/Seal™ |
Symbol | GHS07,GHS08 |
Signal word | Warning |
Hazard statements | H319 - H335 - H351 |
Precautionary statements | P261 - P281 - P305 + P351 + P338 |
Hazard Codes | Xn |
Risk Statements | 19-36/37-40 |
Safety Statements | 26-36/37 |
RIDADR | UN 2924 8(3) / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | No data available |
Flash Point(C) | No data available |
Supplemental Hazard Statements | EUH019 |
bp | 65 °C |
Density | 0.951 g/mL at 25 °C |
Storage Temp. | 2-8°C |
UNSPSC | 12352103 |