1-Naphthylmagnesium bromide solution

ALDRICH/561673 - 0.25 M slurry in THF

CAS Number: 703-55-9
Empirical Formula (Hill Notation): C₁₀H₇BrMg
Molecular Weight: 231.37
MDL Number: MFCD00015768
Linear Formula: C₁₀H₇BrMg
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-561673-50ML	50 mL	$316.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

bp	65 °C
concentration	0.25 M slurry in THF
density	0.908 g/mL at 25 °C
InChI	1S/C10H7.BrH.Mg/c1-2-6-10-8-4-3-7-9(10)5-1;;/h1-7H;1H;/q;;+1/p-1
InChI key	PZIIGUMPOSVMSD-UHFFFAOYSA-M
reaction suitability	reaction type: Grignard Reaction
SMILES string	Br[Mg]c1cccc2ccccc12

Application:	1-Naphthylmagnesium bromide can be used: • To prepare unsymmetrical chiral diene ligands, which are applicable in asymmetric transformation reactions. • As a starting material in the synthesis of methyl (2Z,4E)-2-methylsulfanyl-5-(1-naphthyl)-4-nitro-2,4-pentadienoate, a naphthylnitrobutadiene based anti-proliferative compound.
Legal Information:	Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.
Packaging:	50 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H302 - H314 - H335 - H351
Precautionary statements	P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
Hazard Codes	F,Xn
Risk Statements	11-14-19-36/37/38-40
Safety Statements	16-26-36/37
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	1.4 °F - closed cup
Flash Point(C)	-17 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

bp	65 °C
Density	0.908 g/mL at 25 °C
UNSPSC	12352103

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