3,5-Dichlorophenylmagnesium bromide solution
ALDRICH/562289 - 0.5 M in THF
CAS Number: 82297-90-3
Empirical Formula (Hill Notation): C6H3BrCl2Mg
Molecular Weight: 250.20
MDL Number: MFCD01319892
Linear Formula: Cl2C6H3MgBr
Product Type: Chemical
bp | 65 °C |
concentration | 0.5 M in THF |
density | 0.972 g/mL at 25 °C |
InChI | 1S/C6H3Cl2.BrH.Mg/c7-5-2- |
InChI key | PWOVECVCCCTJFQ-UHFFFAOYSA |
Quality Level | 100 |
reaction suitability | reaction type: Grignard Reaction |
SMILES string | Clc1cc(Cl)cc([Mg]Br)c1 |
storage temp. | 2-8°C |
Application: | 3,5-Dichlorophenylmagnesi • In one of the key synthetic steps for the preparation of non-alternant polycyclic hydrocarbon named indeno-benzophenalene. • As a substrate in the synthesis of carboxylic esters by reacting with 2-methyl-4,6-pyrimidyl dicarbonates. • As a substrate in the synthesis of aryl ketones by reacting with acid chlorides using bis[2-(N,N-dimethylamino)ethyl] ether ligand. |
Legal Information: | Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc. |
Packaging: | 50 mL in Sure/Seal™ |
Symbol | GHS02,GHS05,GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H225 - H302 - H314 - H335 - H351 |
Precautionary statements | P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235 |
Hazard Codes | F,C |
Risk Statements | 11-14-19-34-37-40 |
Safety Statements | 16-26-36/37/39-45 |
RIDADR | UN 2924 8(3) / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Supplemental Hazard Statements | EUH014 - EUH019 |
bp | 65 °C |
Density | 0.972 g/mL at 25 °C |
Storage Temp. | 2-8°C |
UNSPSC | 12352103 |