Diethyl azodicarboxylate solution
ALDRICH/563110 - 40 wt. % in toluene
Synonym: 1,2-Ethoxycarbonyl diazene solution; DEAD; Diethoxycarbonyldiazene solution; Diethyl azodiformate solution; NSC 3474; NSC 679015; Unifoam AZ-AE 200
CAS Number: 1972-28-7
Empirical Formula (Hill Notation): C6H10N2O4
Molecular Weight: 174.15
MDL Number: MFCD00009103
Linear Formula: C2H5OCON=NCOOC2H5
Product Type: Chemical
| bp | 116-117 °C |
| concentration | 40 wt. % in toluene |
| density | 0.956 g/mL at 25 °C |
| InChI | 1S/C6H10N2O4/c1-3-11-5(9) |
| InChI key | FAMRKDQNMBBFBR-BQYQJAHWSA |
| Quality Level | 100  |
| refractive index | n |
| SMILES string | CCOC(=O)N=N/C(=O)OCC |
| storage temp. | 2-8°C |
| Application: | A commonly used activating reagent in Mitsunobo reactions. |
| Application: | Reactant for preparation of: • Immunostimulants α-Galactosylceramides • Cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases • Bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransfer • Derivatives of F200 and S383 with cannabinoid CB1 receptor binding activities • Aza-β-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes Reagent for: • Annulation of N-protected imines • α-thiocyanation of enolizable ketones with ammonium thiocyanate • Diels-Alder reactions |
| General description: | DOT Special Approval Submission is Under Review. Availability is Estimated as March 2012. |
| Packaging: | 100g unit contains ca. 40g DEAD solute |
| Packaging: | 25, 100 g in glass bottle |
| Packaging: | 25g unit contains ca. 10g DEAD solute |
| Warning: | Toxic, Irritant, Flammable |
| Symbol |    GHS02,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H226 - H242 - H304 - H315 - H319 - H335 - H336 - H361d - H373 - H412 |
| Precautionary statements | P210 - P301 + P310 - P331 - P370 + P378 - P403 + P233 - P403 + P235 |
| Hazard Codes | Xn |
| Risk Statements | 63-5-10-20-36/37/38-48/20-65 |
| Safety Statements | 26-36/37-62 |
| RIDADR | UN3379 - DOT UN3223 class 3 - PG 1 - Desensitized explosive, liq |
| WGK Germany | WGK 3 |
| Flash Point(F) | 105.8 °F - closed cup |
| Flash Point(C) | 41 °C - closed cup |
| bp | 116-117 °C |
| Density | 0.956 g/mL at 25 °C |
| Refractive Index | n |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352108 |