9-Phenanthrylmagnesium bromide

ALDRICH/563749 - 0.5 M in THF

CAS Number: 71112-64-6
Empirical Formula (Hill Notation): C₁₄H₉BrMg
Molecular Weight: 281.43
MDL Number: MFCD00672008
Linear Formula: C₁₄H₉BrMg
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-563749-50ML	50 mL	$395.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

bp	65 °C (lit.)
concentration	0.5 M in THF
density	0.970 g/mL at 25 °C (lit.)
InChI	1S/C14H9.BrH.Mg/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13;;/h1-9H;1H;/q;;+1/p-1
InChI key	ACMUZKQPXSHTGB-UHFFFAOYSA-M
Quality Level	100
reaction suitability	reaction type: Grignard Reaction
SMILES string	Br[Mg]c1cc2ccccc2c3ccccc13
storage temp.	2-8°C

Application:	9-Phenanthrylmagnesium bromide can be used as a reagent to prepare: • 9-alkyl and 9-arylthiophenanthrenes by reacting with alkyl or aryl thiol compounds. • (S)-α-methylbenzyl 1-(9-phenanthryl)-2-naphthoate by treating with (S)- α -methylbenzyl methoxy-2-naphthoate. • 1-(9-Phenanthryl)-1-phenylethanol (carbinol) by reacting with acetophenone. The obtained carbinol undergoes dehydration reaction in the presence of acetic acid and sulfuric acid to afford 1-(9-phenanthryl)-1-phenylethene (PPE).
General description:	9-phenanthrylmagnesium bromide is a Grignard reagent. It can be prepared using magnesium turnings and 9-bromophenanthrene under anhydrous condition.
Legal Information:	Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.
Packaging:	50 mL in Sure/Seal™

Symbol	GHS02,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H302 - H319 - H335 - H351
Precautionary statements	P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
Hazard Codes	F,Xn
Risk Statements	11-19-36/37-40
Safety Statements	16-26-36/37
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable
Supplemental Hazard Statements	EUH019

bp	65 °C (lit.)
Density	0.970 g/mL at 25 °C (lit.)
Storage Temp.	2-8°C
UNSPSC	12352103

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