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9-Phenanthrylmagnesium bromide

ALDRICH/563749 - 0.5 M in THF

CAS Number: 71112-64-6
Empirical Formula (Hill Notation): C14H9BrMg
Molecular Weight: 281.43
MDL Number: MFCD00672008
Linear Formula: C14H9BrMg
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-563749-50ML 50 mL
 $359.00
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bp 65 °C (lit.)
concentration 0.5 M in THF
density 0.970 g/mL at 25 °C (lit.)
InChI 1S/C14H9.BrH.Mg/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13;;/h1-9H;1H;/q;;+1/p-1
InChI key ACMUZKQPXSHTGB-UHFFFAOYSA-M
Quality Level 100 
reaction suitability reaction type: Grignard Reaction
SMILES string Br[Mg]c1cc2ccccc2c3ccccc13
storage temp. 2-8°C
Application: 9-Phenanthrylmagnesium bromide can be used as a reagent to prepare:
•  9-alkyl and 9-arylthiophenanthrenes by reacting with alkyl or aryl thiol compounds.
•  (S)-α-methylbenzyl 1-(9-phenanthryl)-2-naphthoate by treating with (S)- α -methylbenzyl methoxy-2-naphthoate.
•  1-(9-Phenanthryl)-1-phenylethanol (carbinol) by reacting with acetophenone. The obtained carbinol undergoes dehydration reaction in the presence of acetic acid and sulfuric acid to afford 1-(9-phenanthryl)-1-phenylethene (PPE).
General description: 9-phenanthrylmagnesium bromide is a Grignard reagent. It can be prepared using magnesium turnings and 9-bromophenanthrene under anhydrous condition.
Legal Information: Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Packaging: 50 mL in Sure/Seal™
bp 65 °C (lit.)
Density 0.970 g/mL at 25 °C (lit.)
Storage Temp. 2-8°C
UNSPSC 12352103

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