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1,1′-Bis(phenylphosphinidene)ferrocene

ALDRICH/567159 - 97%

Synonym: 1,1′-(Ferrocenediyl)phenylphosphine

CAS Number: 72954-06-4
Empirical Formula (Hill Notation): C16H13FeP
Molecular Weight: 292.09
MDL Number: MFCD04974069
Linear Formula: C5H4PC6H5C5H4Fe
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-567159-1G 1 g
 $205.00
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assay 97%
form solid
functional group phosphine
InChI 1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;
InChI key HKOUDNXXOXEYNZ-UHFFFAOYSA-N
mp 88-92 °C (lit.)
reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string [Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3
storage temp. 2-8°C
Application: Reactant for:
• Preparation of macrocyclic tridentate ferrocenylphosphine ligands
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
• Ring-opening reactions via ring slippage
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate
Packaging: 1 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
mp 88-92 °C (lit.)
Storage Temp. 2-8°C
UNSPSC 12352005

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