tert-Butylsulfinyl chloride
ALDRICH/569437 - 97%
Synonym: 1,1-
CAS Number: 31562-43-3
Empirical Formula (Hill Notation): C4H9ClOS
Molecular Weight: 140.63
MDL Number: MFCD04974074
Linear Formula: (CH3)3CS(O)Cl
Product Type: Chemical
| assay | 97% |
| bp | 53-54 °C/19 mmHg (lit.) |
| density | 1.135 g/mL at 25 °C (lit.) |
| InChI | 1S/C4H9ClOS/c1-4(2,3)7(5) |
| InChI key | ZLJKQOWJEZSNBE-UHFFFAOYSA |
| refractive index | n |
| SMILES string | CC(C)(C)S(Cl)=O |
| Application: | tert-butylsulfinyl chloride can react with primary and secondary amines to form tert-butylsulfinamides, which on oxidation forms base stable tert-butylsulfonamide. It can also react with 1-thiosugars to form the corresponding carbohydrate thionolactones. |
| General description: | tert-Butylsulfinyl chloride can be synthesized by using tert-butylmagnesium chloride as the starting material via a multi-step synthesis process. |
| Packaging: | 1, 5 g in glass bottle |
| Symbol |   GHS02,GHS05 |
| Signal word | Danger |
| Hazard statements | H226 - H314 |
| Precautionary statements | P280 - P305 + P351 + P338 - P310 |
| Hazard Codes | C |
| Risk Statements | 10-34 |
| Safety Statements | 16-26-36/37/39-45 |
| RIDADR | UN 2920 3(8) / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | 125.1 °F - closed cup |
| Flash Point(C) | 51.7 °C - closed cup |
| Purity | 97% |
| bp | 53-54 °C/19 mmHg (lit.) |
| Density | 1.135 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |