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N-Allyl-N,N-bis(trimethylsilyl)amine

ALDRICH/578932 - 97%

Synonym: (Prop-2-en-1-yl)bis(trimethylsilyl)amine; 1,1,1-Trimethyl-N-2-propen-1-yl-N-(trimethylsilyl)silanamine; 3-Bis(trimethylsilyl)amino-1-propene; Bis(trimethylsilyl)allylamine; N,N-Bis(trimethylsilyl)-2-propen-1-amine; N,N-Bis(trimethylsilyl)allylamine; N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silanamine

CAS Number: 7688-51-9
Empirical Formula (Hill Notation): C9H23NSi2
Molecular Weight: 201.46
EC Number: 231-699-2
MDL Number: MFCD00545193
Linear Formula: CH2=CHCH2NH[Si(CH3)3]2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-578932-5G 5 g
 $179.00
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assay 97%
bp 72 °C/15 mmHg (lit.)
density 0.816 g/mL at 25 °C (lit.)
form liquid
InChI 1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3
InChI key CVNCFZIIZGNVFD-UHFFFAOYSA-N
Quality Level 100 
refractive index n20/D 1.440 (lit.)
SMILES string C[Si](C)(C)N(CC=C)[Si](C)(C)C
Application: N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:
•  Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
•  Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
•  Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.


AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.
Packaging: 5 g in glass bottle
Purity 97%
bp 72 °C/15 mmHg (lit.)
Density 0.816 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.440 (lit.)
UNSPSC 12352103

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