Chloroform-d
ALDRICH/612200 - 99.8 atom % D, contains 0.05 % (v/v) TMS
Synonym: Deuterochloroform
CAS Number: 865-49-6
Empirical Formula (Hill Notation): CCl3D
Molecular Weight: 120.38
EC Number: 212-742-4
MDL Number: MFCD00000827
Linear Formula: CDCl3
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 612200-100G.
| assay | ≥99% (CP) |
| bp | 60.9 °C (lit.) |
| contains | 0.05 % (v/v) TMS |
| density | 1.500 g/mL at 25 °C (lit.) |
| form | liquid |
| impurities | ≤0.0100% water water |
| InChI | 1S/CHCl3/c2-1(3)4/h1H/i1D |
| InChI key | HEDRZPFGACZZDS-MICDWDOJSA |
| isotopic purity | 99.8 atom % D |
| mass shift | M+1 |
| mp | −64 °C (lit.) |
| Quality Level | 100  |
| refractive index | n |
| SMILES string | [2H]C(Cl)(Cl)Cl |
| technique(s) | NMR: suitable |
| Application: | Chloroform-d may be used in the synthesis of dichlorofluoromethane-d. |
| General description: | Chloroform-d (deuterochloroform, CDCl3) is a deuterated NMR solvent containing 0.05% (v/v) TMS (tetramethylsilane). It is useful in NMR-based research and analyses. It may be synthesized by reacting trichloroacetophenone and sodium deuteroxide. The influence of the number of pulses on its multiphoton decomposition (MPD) has been studied. Infrared spectral studies of C-D stretching and bending motions of CDCl3 in different solvents have been investigated. The effect of chloroform-d on the interaction of water with activated carbons has been analyzed. The dependence of molecular reorientation of deuterated chloroform on pressure and temperature has been studied by Raman spectroscopy. |
| Packaging: | 1 kg in glass bottle |
| Packaging: | 100, 10×100 g in glass bottle |
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| Symbol |   GHS06,GHS08 |
| Signal word | Danger |
| Hazard statements | H302 - H315 - H319 - H331 - H336 - H351 - H361d - H372 |
| Precautionary statements | P202 - P301 + P312 - P302 + P352 - P304 + P340 + P311 - P305 + P351 + P338 - P308 + P313 |
| Hazard Codes | Xn |
| Risk Statements | 63-20/22-36/38-40-48/20 |
| Safety Statements | 36/37 |
| RIDADR | UN 1888 6.1 / PGIII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥99% (CP) |
| bp | 60.9 °C (lit.) |
| mp | −64 °C (lit.) |
| Density | 1.500 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12142201 |