DavePhos
ALDRICH/638021 - 97%
Synonym: 2-
CAS Number: 213697-53-1
Empirical Formula (Hill Notation): C26H36NP
Molecular Weight: 393.54
MDL Number: MFCD02183572
Linear Formula: C26H36NP
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 638021-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 638021-25G
| assay | 97% |
| functional group | phosphine |
| InChI | 1S/C26H36NP/c1-27(2)25-19 |
| InChI key | ZEMZPXWZVTUONV-UHFFFAOYSA |
| mp | 121-124 °C (lit.) |
| Quality Level | 200  |
| reaction suitability | reaction type: Cross Couplings |
| reagent type: ligand reaction type: Arylations |
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| reagent type: ligand reaction type: Buchwald-Hartwig Cross Coupling Reaction |
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| reagent type: ligand reaction type: Hydroaminations |
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| reagent type: ligand reaction type: Kumada Coupling |
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| reagent type: ligand reaction type: Negishi Coupling |
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| reagent type: ligand reaction type: Suzuki-Miyaura Coupling |
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| SMILES string | CN(C)c1ccccc1-c2ccccc2P(C |
| Application: | DavePhos may be used as a ligand in the following reactions: • Palladium catalyzed sp3 arylation of 2-substituted-N-iminopyridinium ylides with different aryl chlorides to yield functionalized pyridines. • Preparation of functionalized benzylic sulfones via palladium-catalyzed Negishi cross-coupling between alkyl sulfones and aryl halides. • C-C Coupling of 3-haloquinolines with aryl sulfinates via palladium-catalyzed desulfitative arylation to form the corresponding biaryl compounds. |
| Application: | Ligand used in a Pd-catalyzed Suzuki aryl-aryl coupling leading to benzodioxepines. Learn more about Buchwald Phosphine Ligands |
| Application: | Useful ligand for Pd-catalyzed C-N bond formation; amination of aryl halides containing hydroxyl, amide, or enolizable ketones. |
| Legal Information: | Usage subject to US Patents 6307087 and 6395916. |
| Packaging: | 1, 5, 25, 100 g in glass bottle |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 97% |
| mp | 121-124 °C (lit.) |
| UNSPSC | 12352116 |