Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate

ALDRICH/640360

Synonym: [Rh(cod)(MeCN)₂]BF₄

CAS Number: 32679-02-0
Empirical Formula (Hill Notation): C₁₂H₁₈BF₄N₂Rh
Molecular Weight: 379.99
MDL Number: MFCD06798085
Linear Formula: C₁₂H₁₈BF₄N₂Rh
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-640360-1G	1 g	$557.00 1/EA		Add To Favorites
45-640360-5G	5 g	$2630.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	solid
InChI	1S/C8H12.2C2H3N.BF4.Rh/c1-2-4-6-8-7-5-3-1;21-2-3;2-1(3,4)5;/h1-2,7-8H,3-6H2;21H3;;/q;;;-1;+1/b2-1-,8-7-;;;;
InChI key	KSMAFOANQHYEJG-SUESZSCISA-N
Quality Level	100
reaction suitability	core: rhodium
	reagent type: catalyst
SMILES string	[Rh+].CC#N.CC#N.F[B-](F)(F)F.C1CC=CCCC=C1

Application:	Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate [Rh(cod)(MeCN)₂]BF₄may be used as a catalyst for the rhodium(I)-catalyzed silylation of aryl iodides and bromides with tetraethoxysilanes to form aryl silanes such as (4-bromophenyl)triethoxysilane and 4-(triethoxysilyl)acetophenone.
Packaging:	1, 5 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

UNSPSC

12161600

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