Chlorodicyclopentylphosphine

ALDRICH/649066 - 97%

Synonym: Dicyclopentylchlorophosphine; Dicyclopentylphosphine chloride

CAS Number: 130914-24-8
Empirical Formula (Hill Notation): C₁₀H₁₈ClP
Molecular Weight: 204.68
MDL Number: MFCD06798131
Linear Formula: C₁₀H₁₈ClP
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-649066-5G	5 g	$264.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
density	1.069 g/mL at 25 °C (lit.)
functional group	phosphine
InChI	1S/C10H18ClP/c11-12(9-5-1-2-6-9)10-7-3-4-8-10/h9-10H,1-8H2
InChI key	QTYRJBRBODDGCQ-UHFFFAOYSA-N
Quality Level	100
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
SMILES string	ClP(C1CCCC1)C2CCCC2

Application:	Chlorodicyclopentylphosphine may be used to prepare: • Cp,Cp-MannOP, a chiral diphosphinite ligand by reacting with mannitol.[Cp=cyclopentyl; Mann=mannitol] • (S)-Cp,Cp-oxoProNOP, a bis(dicycloalkylphosphino) amidophosphine-phosphinite ligand by reacting with (S)-5-(hydroxymethyl)-2-pyrrolidinone • L^cPeNiCl, a precursor for preparing L^cPeNiH, which is an efficient catalyst for the reduction of CO₂[cPe=cyclopentyl]
General description:	Chlorodicyclopentylphosphine is a phosphine precursor for ligand preparation in Negishi and Suzuki coupling reactions.
General description:	http://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.259.5096&rep=rep1&type=pdf
Packaging:	1, 5 g in glass bottle

Symbol	GHS05
Signal word	Danger
Hazard statements	H314
Precautionary statements	P280 - P305 + P351 + P338 - P310
Hazard Codes	C
Risk Statements	14-34
Safety Statements	26-36/37/39-45
RIDADR	UN 3265 8 / PGII
WGK Germany	WGK 3
Flash Point(F)	230.0 °F - closed cup
Flash Point(C)	> 110 °C - closed cup
Supplemental Hazard Statements	EUH014

Purity	97%
Density	1.069 g/mL at 25 °C (lit.)
UNSPSC	12352101

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