Synonym: (R)-1-Methyl-3,3-diphenylhexahydropyrrolo[1,2-c][1,3,2]oxazaborole; (R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole; (R)-Me-Corey-Bakshi-Shibata catalyst
CAS Number: 112022-83-0
Empirical Formula (Hill Notation): C18H20BNO
Molecular Weight: 277.17
MDL Number: MFCD00078440
Linear Formula: C18H20BNO
Product Type: Chemical
| assay |
≥90% |
| form |
solid |
| InChI |
1S/C18H20BNO/c1-19-20-14-8-13-17(20)18(21-19,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17H,8,13-14H2,1H3/t17-/m1/s1 |
| InChI key |
VMKAFJQFKBASMU-QGZVFWFLSA-N |
| mp |
85-95 °C (lit.) |
| SMILES string |
CB1OC(C2CCCN12)(c3ccccc3)c4ccccc4 |
| Application: |
CBS Catalysts for Asymmetric Reduction and Asymmetric Synthesis   |
| Application: |
The CBS (Corey-Bakshi-Shibata) oxazaborolidine catalyst has been used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2 symmetrical ferrocenyl diols, and propargyl alcohols. |
| Packaging: |
1, 10 g in glass bottle |
| RIDADR |
NONH for all modes of transport |
| WGK Germany |
WGK 3 |
| Flash Point(F) |
Not applicable |
| Flash Point(C) |
Not applicable |
| Purity |
≥90% |
| mp |
85-95 °C (lit.) |
| UNSPSC |
12352005 |
