Tetrabutylammonium azide
ALDRICH/651664
Synonym: N,N,N-
CAS Number: 993-22-6
Empirical Formula (Hill Notation): C16H36N4
Molecular Weight: 284.48
MDL Number: MFCD00060069
Linear Formula: C16H36N4
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 651664-25G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 651664-5G
| form | solid |
| functional group | amine |
| azide | |
| InChI | 1S/C16H36N.N3/c1-5-9-13-1 |
| InChI key | GMRIOAVKKGNMMV-UHFFFAOYSA |
| mp | 84-88 °C (lit.) |
| Quality Level | 200  |
| reaction suitability | reaction type: click chemistry |
| SMILES string | [N-]=[N+]=[N-].CCCC[N+](C |
| storage temp. | 2-8°C |
| Application: | Reagent for synthesis of: • Heteroarylannulated bicyclic morpholines • Cyanimide-based inhibitors of cathepsin C • Trimethylene carbonate Reagent for: • Aerobic oxidative transformation of primary azides to nitriles • Substitution reactions at tetracoordinate boron Catalyst for syslic carbonate formation |
| Application: | Tetrabutylammonium azide can be used as a reagent for the synthesis of: • Heteroarylannulated bicyclic morpholines • Cyanimide-based inhibitors of cathepsin C • Trimethylene carbonate • Aerobic oxidative transformation of primary azides to nitriles • Substitution reactions at tetracoordinate boron It is also used as a catalyst for cyclic carbonate formation. |
| Packaging: | 5, 25 g in glass bottle |
| Symbol |   GHS06,GHS09 |
| Signal word | Danger |
| Hazard statements | H301 - H315 - H319 - H335 - H410 |
| Precautionary statements | P273 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | T,N |
| Risk Statements | 25-32-36/37/38-50/53 |
| Safety Statements | 26-45-60-61 |
| RIDADR | UN2811 - class 6.1 - PG 3 - EHS - Toxic solids, organic, n.o.s., |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Supplemental Hazard Statements | EUH032 |
| mp | 84-88 °C (lit.) |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352116 |