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(S)-1-{(SP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine

ALDRICH/65672 - ≥97%

Synonym: (1R)-1-[(1S)-1-[Bis(3,5-bis(trifluoromethyl)phenyl)phosphino]ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene (acc to CAS); Walphos SL-W001-2

CAS Number: 849925-17-3
Empirical Formula (Hill Notation): C46H32F12FeP2
Molecular Weight: 930.52
MDL Number: MFCD04117710
Linear Formula: C46H32F12FeP2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-65672-100MG 100 mg
 $107.00
1/EA		 Add To Favorites
45-65672-500MG 500 mg
 $0.00
1/EA
CALL FOR PRICE		 Add To Favorites

 

assay ≥97%
InChI 1S/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m1../s1
InChI key LKNKYBWIZNAXBY-KHZPMNTOSA-N
optical purity ee: ≥99%
SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F
Application: (S)-1-{(SP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine can be used:
•  To prepare sulfide-capped triruthenium hydrido clusters containing Walphos ligands, which are employed as catalysts for asymmetric hydrogenation of tiglic acid (trans-2-methyl-2-butenoic acid).
•  As a ligand in the reductive allylic alkylation of unsaturated carbonyl compounds using Pd catalyst.
General description: sold in collaboration with Solvias AG
Packaging: 1, 5 g in glass bottle
Packaging: 100, 500 mg in glass bottle
Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity ≥97%
UNSPSC 12352101

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