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Di-μ-chlorotetraethylene dirhodium(I)

ALDRICH/656763

Synonym: Bis[chlorobis(ethylene)rhodium]; Bis[chlorodiethylenerhodium]; Chlorobis(ethylene)rhodium dimer; Dichlorotetra(ethene)dirhodium; Dichlorotetrakis(ethene)dirhodium; Diethylenerhodium chloride dimer; Divinylrhodium chloride dimer; Tetrakis(ethylene)dichlorodirhodium; [Rh(C2H4)2Cl]2

CAS Number: 12081-16-2
Empirical Formula (Hill Notation): C8H16Cl2Rh2
Molecular Weight: 388.93
EC Number: 235-145-0
MDL Number: MFCD00013206
Linear Formula: C8H16Cl2Rh2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-656763-100MG 100 mg
 $129.00
1/EA		 Add To Favorites
45-656763-1G 1 g
 $710.00
1/EA		 Add To Favorites

 

form solid
InChI 1S/4C2H4.2ClH.2Rh/c4*1-2;;;;/h4*1-2H2;2*1H;;/q;;;;;;2*+1/p-2
InChI key OOQJCPOXJFCGCR-UHFFFAOYSA-L
reaction suitability core: rhodium
  reagent type: catalyst
SMILES string Cl[Rh].Cl[Rh].C=C.C=C.C=C.C=C
storage temp. −20°C
Application: Di-μ-chlorotetraethylene dirhodium(I) may be used in the preparation of Π-bound rhodium organometallic complexes of ROMP-derived poly(1,5-cyclooctadiene) (poly(COD)). [ROMP= Ring-Opening Metathesis Polymerization; COD= 1,5-cyclooctadiene]
Application: Precursor to Rh(I) norbornadiene catalyst used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones.
Packaging: 1 g in glass bottle
Packaging: 100 mg in glass bottle
Symbol GHS07  GHS07
Signal word Warning
Hazard statements H319
Precautionary statements P305 + P351 + P338
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Storage Temp. −20°C
UNSPSC 12161600

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