Di-μ-chlorotetraethylene dirhodium(I)
ALDRICH/656763
Synonym: Bis[chlorobis(ethylene)
CAS Number: 12081-16-2
Empirical Formula (Hill Notation): C8H16Cl2Rh2
Molecular Weight: 388.93
EC Number: 235-145-0
MDL Number: MFCD00013206
Linear Formula: C8H16Cl2Rh2
Product Type: Chemical
| form | solid |
| InChI | 1S/4C2H4.2ClH.2Rh/c4*1-2; |
| InChI key | OOQJCPOXJFCGCR-UHFFFAOYSA |
| Quality Level | 100 ![]() |
| reaction suitability | core: rhodium |
| reagent type: catalyst | |
| SMILES string | Cl[Rh].Cl[Rh].C=C.C=C.C=C |
| storage temp. | −20°C |
| Application: | Di-μ-chlorotetraethylene dirhodium(I) may be used in the preparation of Π-bound rhodium organometallic complexes of ROMP-derived poly(1,5-cyclooctadiene) (poly(COD)). [ROMP= Ring-Opening Metathesis Polymerization; COD= 1,5-cyclooctadiene] |
| Application: | Precursor to Rh(I) norbornadiene catalyst used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones. |
| Packaging: | 1 g in glass bottle |
| Packaging: | 100 mg in glass bottle |
| Symbol | GHS07 |
| Signal word | Warning |
| Hazard statements | H319 |
| Precautionary statements | P305 + P351 + P338 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Storage Temp. | −20°C |
| UNSPSC | 12161600 |


