Isopropylmagnesium chloride lithium chloride complex solution

ALDRICH/656984 - 1.3 M in THF

Synonym: Turbo Grignard

Empirical Formula (Hill Notation): C₃H₇Cl₂LiMg
Molecular Weight: 145.24
MDL Number: MFCD07784514
Linear Formula: (CH₃)₂CHMgCl · LiCl
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-656984-4X25ML	25 mL	$135.00 4/EA		Add To Favorites
45-656984-100ML	100 mL	$131.00 1/EA		Add To Favorites
45-656984-800ML	800 mL	$426.00 1/EA		Add To Favorites
45-656984-2L	2 L	$661.00 1/EA		Add To Favorites

25 mL Sure/Seal™ Packaging

Properties
Descriptions
Safety Info.
Basic Data

concentration	1.3 M in THF
density	0.951 g/mL at 25 °C
InChI	1S/C3H7.2ClH.Li.Mg/c1-3-2;;;;/h3H,1-2H3;21H;;/q;;;2+1/p-2
InChI key	CWTUREABAILGIK-UHFFFAOYSA-L
Quality Level	100
	200
reaction suitability	reaction type: Grignard Reaction
SMILES string	[Li]Cl.CC(C)[Mg]Cl

Application:	Reagent for Selective Metalations Used for: • Preparation of functionalized acyclic alkenyl magnesium reagents/preparation of 1,2-diketones • Preparation of cyclic alkenyl and dienyl magnesium reagents • Preparation of functionalized triazenes/preparation of carbazoles • Regioselective functionalization of trisubstituted pyridines • Electrophilic amination for preparation of amines • Preparation of Grignards reagents in the presence of masked ketones and aldehydes (using readily deprotectable silylated cyanohydrins) • Preparation of Benzylic Grignards via Sulfur-Magnesium exchange • Functionalization via I-Mg Exchange of unprotected aromatic and heteroaromatic carboxylic acids • Functionalization via I-Mg Exchange of unprotected imidazoles • Pyridyne formation • Functionalization of cyclopentene derivatives • Preparation of 2,3-functionalized furans, benzofurans, and thiophenes • Stereoselective synthesis of substituted cyclopropanes
Application:	Reagent used with CH₃MgCl/LiCl to affect magnesium-halogen exchange on unprotected aryl carboxylic acids.
Legal Information:	Product of Albemarle US Inc
Legal Information:	Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging:	2 L in Sure/Seal™
Packaging:	4×25, 100, 800 mL in Sure/Seal™
Packaging:	The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H314 - H335 - H351
Precautionary statements	P201 - P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310
Hazard Codes	F,C
Risk Statements	11-14/15-19-34-37-40
Safety Statements	16-26-36/37/39-43-45
RIDADR	UN 3399BC 4.3(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	1.4 °F
Flash Point(C)	-17 °C
Supplemental Hazard Statements	EUH014 - EUH018 - EUH019

Density	0.951 g/mL at 25 °C
UNSPSC	12352103

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