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Hydroxy(cyclooctadiene)rhodium(I) dimer

ALDRICH/661023 - 95%

Synonym: (Cyclooctadiene)rhodium hydroxide dimer; 1,5-Cyclooctadiene)hydroxyrhodium dimer; Bis(cyclooctadiene)dihydroxodirhodium; Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di--μ-hydroxydirhodium; Bis[(1,5-cyclooctadiene)(hydroxy)rhodium]; [Rh(OH)(1,5-cod)]2

CAS Number: 73468-85-6
Empirical Formula (Hill Notation): C16H26O2Rh2
Molecular Weight: 456.19
MDL Number: MFCD08457638
Linear Formula: C16H26O2Rh2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-661023-250MG 250 mg
 $341.00
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45-661023-1G 1 g
 $379.00
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12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

 

assay 95%
form solid
greener alternative category Aligned ,  
greener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry .
InChI 1S/2C8H12.2H2O.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H2;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
InChI key IUAQXTGDGDIMOD-MIXQCLKLSA-L
mp 199 °C (dec.)
Quality Level 100 
reaction suitability core: rhodium
  reagent type: catalyst
SMILES string O[Rh].O[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
sustainability Greener Alternative Product
Application: Efficient and Selective Catalysts for Asymmetric Synthesis 
Application: Catalyst for oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids 
Application: Rhodium catalyst employed with R-BINAP or R-SEGPHOS® ligands in a synthesis of chiral 3,3-disubstituted-1-indanones.
General description: We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here  for more information.
Legal Information: SEGPHOS is a registered trademark of Takasago Intl. Corp.
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 95%
mp 199 °C (dec.)
UNSPSC 12352300

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