Methoxy(cyclooctadiene)rhodium(I) dimer

ALDRICH/661058

Synonym: [Rh(OMe)(1,5-cod)]₂

CAS Number: 12148-72-0
Empirical Formula (Hill Notation): C₁₈H₃₀O₂Rh₂
Molecular Weight: 484.24
MDL Number: MFCD08457639
Linear Formula: C₁₈H₃₀O₂Rh₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-661058-250MG	250 mg	$238.00 1/EA		Add To Favorites
45-661058-1G	1 g	$652.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	solid
InChI	1S/2C8H12.2CH3O.2Rh/c21-2-4-6-8-7-5-3-1;21-2;;/h21-2,7-8H,3-6H2;21H3;;/q;;2-1;2+1/b2*2-1-,8-7-;;;;
InChI key	BDQMDBOKWREKIT-MIXQCLKLSA-N
mp	192-225 °C
Quality Level	100
reaction suitability	core: rhodium
	reagent type: catalyst
SMILES string	CO[Rh].CO[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
storage temp.	−20°C

Application:	Efficient and Selective Catalysts for Asymmetric Synthesis
Application:	Precursor for organorhodium(I) species, catalyst for cascade1,4-addition-aldol reaction, 1,4-addition of alcohols, and hydroformylation
Application:	Rhodium catalyst employed in the cyclization of cyano-substituted unsaturated esters in the presence of aryl 9-BBN leading to 5- and 6-membered β-enamino esters.
Packaging:	1 g in glass bottle
Packaging:	250 mg in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	192-225 °C
Storage Temp.	−20°C
UNSPSC	12352300

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