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Bis(tert-butylcarbonyloxy)iodobenzene

ALDRICH/662283 - 97%

Synonym: (Di-tert-butylcarbonyloxyiodo)benzol; 2,2-Dimethylpropanoic acid, phenyliodine complex; Bis(2,2-dimethylpropanoato-O)phenyliodide; Di-(Pivaloyloxy)iodobenzene

CAS Number: 57357-20-7
Empirical Formula (Hill Notation): C16H23IO4
Molecular Weight: 406.26
MDL Number: MFCD08276835
Linear Formula: C16H23IO4
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-662283-5G 5 g
 $163.00
1/EA		 Add To Favorites
45-662283-25G 25 g
 $323.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 662283-5G

 

assay 97%
form solid
InChI 1S/C16H23IO4/c1-15(2,3)13(18)20-17(12-10-8-7-9-11-12)21-14(19)16(4,5)6/h7-11H,1-6H3
InChI key DZKPLZUSZXYHFB-UHFFFAOYSA-N
mp 104-109 °C
reaction suitability reagent type: catalyst
reaction type: C-H Activation
  reagent type: oxidant
SMILES string CC(C)(C)C(=O)O[I](OC(=O)C(C)(C)C)c1ccccc1
Application: Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination 

Reagent for:
• Preparation of α,β-unsaturated-γ-lactams via Rh-catalyzed C-H amination of allene carbamates, then Ru-catalyzed cyclocarbonylation
• Palladium-catalyzed diamination
• Preparation of functionalized bicyclic heterocyclic compounds by rhodium-catalyzed allene amidation and cyclization
• Preparation of piperidine and pyrrolidine derivatives via copper-catalyzed intramolecular aminoacetoxylation of aminoolefins
• C-H acyloxylation of arenes

• Hypervalent iodine oxidant
Application: Hypervalent iodine reagent used with the Rh2(esp)2 catalyst (662623) in the amination of C-H bonds.
Packaging: 5, 25 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
mp 104-109 °C
UNSPSC 12352002

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