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Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)

ALDRICH/665096 - 97%

Synonym: Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium

CAS Number: 108695-90-5
Empirical Formula (Hill Notation): C20H21Cl3O2PReS
Molecular Weight: 648.98
MDL Number: MFCD08276862
Linear Formula: C20H21Cl3O2PReS
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-665096-250MG 250 mg
 $0.00
1/EA
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45-665096-1G 1 g
 $306.00
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assay 97%
form powder
InChI 1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3
InChI key GIBDGLAUIKUJJX-UHFFFAOYSA-K
reaction suitability core: rhenium
  reagent type: catalyst
SMILES string CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
Application: Catalyst for:
• Enantioselective reduction of ketones and imines
• Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
• Synthesis of 2-deoxy-α glycosides
• Sulfurization of phosphorous(III) compounds with thiiranes

Reactant for synthesis of mono and dinuclear compounds

Reagent for rhenium-cyclized somatostatine derivative series synthesis
Packaging: 1, 5 g in glass bottle
Packaging: 250 mg in glass bottle
Purity 97%
UNSPSC 12161600

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