(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
ALDRICH/665290 - 97%
Synonym: (+)-N,N-Bis[(1S)-1-phenylethyl]- dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin- 4-amine, (11bR)
CAS Number: 380230-02-4
Empirical Formula (Hill Notation): C36H30NO2P
Molecular Weight: 539.60
MDL Number: MFCD04117688
Linear Formula: C36H30NO2P
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 665290-100MG.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 665290-500MG.
| assay | 97% |
| form | solid |
| InChI | 1S/C36H30NO2P/c1-25(27-13 |
| InChI key | LKZPDRCMCSBQFN-UIOOFZCWSA |
| mp | 88-89 °C |
| SMILES string | C[C@H](N([C@@H](C)c1ccccc |
| Application: | DSM MonoPhos Family of Highly Efficient Privileged Ligands  |
| Application: | Chiral phosphoramidite ligand used in a highly enantioselective copper-catalyzed conjugate addition of diakylzincs to a variety of Michael acceptors. Also used in a palladium-catalyzed diethylzinc mediated umpolung allylation. |
| Application: | The product may be used as a ligand in: • Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols. • Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively. • Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives. |
| Features and Benefits: | Advantages of the MonoPhos® ligands: • Superior enantiocontrol in numerous transformations • High activities at low catalyst loadings • Hydrogenations under low-pressure conditions |
| Legal Information: | MonoPhos is a registered trademark of DSM IP Assets B.V. |
| Legal Information: | Sold under license from DSM for research purposes only. |
| Packaging: | 100, 500 mg in glass insert |
| Packaging: | 2 g in glass bottle |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 97% |
| mp | 88-89 °C |
| UNSPSC | 12352005 |