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(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a′]dinaphthalen-4-yl)methylamine

ALDRICH/665355 - 97%

Synonym: (+)-N-Benzyl-N-methyl-dinaphtho[2,1-d:1′,2′]dioxaphosphepin-4-amine, (11bS)

CAS Number: 490023-37-5
Empirical Formula (Hill Notation): C28H22NO2P
Molecular Weight: 435.45
MDL Number: MFCD04117686
Linear Formula: C28H22NO2P
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-665355-100MG 100 mg
 $67.60
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 665355-100MG.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 665355-500MG.

 

assay 97%
form solid
InChI 1S/C28H22NO2P/c1-29(19-20-9-3-2-4-10-20)32-30-25-17-15-21-11-5-7-13-23(21)27(25)28-24-14-8-6-12-22(24)16-18-26(28)31-32/h2-18H,19H2,1H3
InChI key OHGGHRJGBXAKKY-UHFFFAOYSA-N
mp 155-159 °C
SMILES string CN(Cc1ccccc1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56
Application: DSM MonoPhos Family of Highly Efficient Privileged Ligands 
Application: Phosphoramidite ligand used in a rhodium-catalyzed enantioselective 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds. Also used in asymmetric hydrogenation of N-acylated β-dehydroamino esters to enantiopure β-amino acid derivatives.
Legal Information: Sold under license from DSM for research purposes only.
Packaging: 100, 500 mg in glass insert
Packaging: 2 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
mp 155-159 °C
UNSPSC 12352005

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