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(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine

ALDRICH/665363 - 95% (HPLC)

Synonym: (+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine, (11bS)

CAS Number: 497883-22-4
Empirical Formula (Hill Notation): C36H30NO2P
Molecular Weight: 539.60
MDL Number: MFCD08561138
Linear Formula: C36H30NO2P
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-665363-100MG 100 mg
 $70.00
1/EA		 Add To Favorites
45-665363-500MG 500 mg
 $333.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 665363-100MG.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 665363-500MG.

 

assay 95% (HPLC)
functional group amine
  phenyl
InChI 1S/C36H30NO2P/c1-25(27-13-5-3-6-14-27)37(26(2)28-15-7-4-8-16-28)40-38-33-23-21-29-17-9-11-19-31(29)35(33)36-32-20-12-10-18-30(32)22-24-34(36)39-40/h3-26H,1-2H3/t25-,26-/m1/s1
InChI key LKZPDRCMCSBQFN-CLJLJLNGSA-N
mp 102-103 °C
Quality Level 100 
SMILES string C[C@@H](N([C@H](C)c1ccccc1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56)c7ccccc7
Application: DSM MonoPhos Family of Highly Efficient Privileged Ligands 
Application: Chiral phosphoramidite ligand used in a highly enantioselective copper-catalyzed conjugate addition of diakylzincs to a variety of Michael acceptors. Also used in a palladium-catalyzed diethylzinc mediated umpolung allylation.
Features and Benefits: Advantages of the MonoPhos® ligands:
• Superior enantiocontrol in numerous transformations
• High activities at low catalyst loadings
• Hydrogenations under low-pressure conditions
Legal Information: MonoPhos is a registered trademark of DSM IP Assets B.V.
Legal Information: Sold under license from DSM for research purposes only.
Packaging: 100, 500 mg in glass insert
Packaging: 2 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 95% (HPLC)
mp 102-103 °C
UNSPSC 12352005

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