(3aR,8aR)-(−)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine
ALDRICH/665460 - 96%
CAS Number: 213843-90-4
Empirical Formula (Hill Notation): C33H34NO4P
Molecular Weight: 539.60
MDL Number: MFCD04117685
Linear Formula: C33H34NO4P
Product Type: Chemical
assay | 96% |
form | solid |
InChI | 1S/C33H34NO4P/c1-31(2)35- |
InChI key | DRPNADVMTMEWQY-LOYHVIPDSA |
mp | 218-221 °C |
SMILES string | CN(C)P1OC([C@@H]2OC(C)(C) |
Application: | DSM MonoPhos Family of Highly Efficient Privileged Ligands |
Application: | Phosphoramidite ligand employed in an asymmetric, iridium-catalyzed, allylic allylation of propenylboronates. Also used in a copper-catalyzed asymmetric conjugate addition of diethylzinc to α,β-unsaturated imines derived from amino acids. |
Legal Information: | Sold under license from DSM for research purposes only. |
Packaging: | 100 mg in clear glass bottle |
Packaging: | 500 mg in amber glass bottle |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 96% |
mp | 218-221 °C |
UNSPSC | 12352005 |