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(3aR,8aR)-(−)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine

ALDRICH/665460 - 96%

CAS Number: 213843-90-4
Empirical Formula (Hill Notation): C33H34NO4P
Molecular Weight: 539.60
MDL Number: MFCD04117685
Linear Formula: C33H34NO4P
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-665460-500MG 500 mg
$510.00
1/EA
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assay 96%
form solid
InChI 1S/C33H34NO4P/c1-31(2)35-29-30(36-31)33(27-21-13-7-14-22-27,28-23-15-8-16-24-28)38-39(34(3)4)37-32(29,25-17-9-5-10-18-25)26-19-11-6-12-20-26/h5-24,29-30H,1-4H3/t29-,30-/m1/s1
InChI key DRPNADVMTMEWQY-LOYHVIPDSA-N
mp 218-221 °C
SMILES string CN(C)P1OC([C@@H]2OC(C)(C)O[C@H]2C(O1)(c3ccccc3)c4ccccc4)(c5ccccc5)c6ccccc6
Application: DSM MonoPhos Family of Highly Efficient Privileged Ligands 
Application: Phosphoramidite ligand employed in an asymmetric, iridium-catalyzed, allylic allylation of propenylboronates. Also used in a copper-catalyzed asymmetric conjugate addition of diethylzinc to α,β-unsaturated imines derived from amino acids.
Legal Information: Sold under license from DSM for research purposes only.
Packaging: 100 mg in clear glass bottle
Packaging: 500 mg in amber glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 96%
mp 218-221 °C
UNSPSC 12352005

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