Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)

ALDRICH/667234

Synonym: Cp*RuCl(cod); 1,5-Cyclooctadiene, ruthenium complex; Chloro(1,5-cyclooctadiene)(η⁵-pentamethylcyclopentadienyl)ruthenium; Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium

CAS Number: 92390-26-6
Empirical Formula (Hill Notation): C₁₈H₂₇ClRu
Molecular Weight: 379.93
MDL Number: MFCD07369035
Linear Formula: C₁₈H₂₇ClRu
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-667234-250MG	250 mg	$135.00 1/EA	Add To Favorites
45-667234-1G	1 g	$361.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 667234-250MG

Properties
Descriptions
Safety Info.
Basic Data

InChI	1S/C10H15.C8H12.ClH.Ru/c1-6-7(2)9(4)10(5)8(6)3;1-2-4-6-8-7-5-3-1;;/h1-5H3;1-2,7-8H,3-6H2;1H;/q;;;+1/p-1/b;2-1-,8-7-;;
InChI key	MQMQNIQJGNBEMG-ONEVTFJLSA-M
mp	143-147 °C
reaction suitability	core: ruthenium
	reagent type: catalyst
SMILES string	Cl[Ru].C1CC=CCCC=C1.C[C]2[C](C)[C](C)[C](C)[C]2C
storage temp.	−20°C

Application:	Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds. It can be used: • To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides. • To catalyze C-C coupling of norbornenes and norbornadiene with alkynes to form [2 + 2] cycloadducts. • In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols. • To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines. • To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.
Packaging:	1 g in glass bottle
Packaging:	250 mg in glass bottle

Symbol	GHS02
Signal word	Danger
Hazard statements	H261
Precautionary statements	P231 + P232 - P422
Hazard Codes	F
Risk Statements	14/15
Safety Statements	43
RIDADR	UN 3395 4.3 / PGII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	143-147 °C
Storage Temp.	−20°C
UNSPSC	12161600

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