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(−)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane

ALDRICH/667811

CAS Number: 528565-79-9
Empirical Formula (Hill Notation): C34H36P2
Molecular Weight: 506.60
MDL Number: MFCD07369027
Linear Formula: C34H36P2
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-667811-100MG 100 mg
$114.00
1/EA
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45-667811-500MG 500 mg
$432.00
1/EA
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form solid
InChI 1S/C34H36P2/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30/h1-20,31-34H,21-26H2/t31-,32-,33-,34-/m1/s1
InChI key VHHAZLMVLLIMHT-YFRBGRBWSA-N
mp 143-147 °C
Quality Level 100 
SMILES string C1C[C@@H](P(CCP2[C@H](CC[C@@H]2c3ccccc3)c4ccccc4)[C@H]1c5ccccc5)c6ccccc6
Application: (−)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane can be used:
• As a chiral ligand in the 1,3-dipolar cycloaddition reaction of azomethyne yielded [70]fullerene enantiomers; catalyzed by silver.
• As a component of the catalytic system along with silver, which is used for the synthesis of fullerene hybrids.

Application: DuPhos and BPE Ligands: Highly Efficient Privileged Ligands 
Legal Information: Sold in collaboration with Namena Corp. for research purposes only.
Packaging: 100, 500 mg in amber glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
mp 143-147 °C
UNSPSC 12352005

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