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(+)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]ethane

ALDRICH/668478 - kanata purity

Synonym: (R,R)-Et-BPE

CAS Number: 136705-62-9
Empirical Formula (Hill Notation): C18H36P2
Molecular Weight: 314.43
MDL Number: MFCD01073768
Linear Formula: C18H36P2
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-668478-100MG 100 mg
$94.20
1/EA
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45-668478-500MG 500 mg
$287.00
1/EA
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bp 104-106 °C/0.05 mmHg
density 0.939 g/mL at 25 °C
InChI 1S/C18H36P2/c1-5-15-9-10-16(6-2)19(15)13-14-20-17(7-3)11-12-18(20)8-4/h15-18H,5-14H2,1-4H3/t15-,16-,17-,18-/m1/s1
InChI key QOLRLVPABLMMKI-BRSBDYLESA-N
Quality Level 100 
refractive index n20/D 1.5249
SMILES string CC[C@@H]1CC[C@@H](CC)P1CCP2[C@H](CC)CC[C@H]2CC
Application: (+)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]ethane can be used as a reactant to prepare:
•  Chromium diphosphine chloride complex which is employed as a catalyst for chemoselective oligomerization reaction.
•  α-Arylpyrrolidines by Suzuki-Miyaura cross-coupling and enantioselective copper-catalyzed intramolecular hydroamination reactions.

It can also be used as a catalyst in the enantioselective preparation of (perfluoroalkyl)butenyldiketones via cross Rauhut-Currier reaction of β-perfluoroalkylenones and vinyl ketones.
Application: DuPhos and BPE Ligands: Highly Efficient Privileged Ligands 
Legal Information: Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.
Packaging: 100 mg in clear glass bottle
Packaging: 500 mg in amber glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
bp 104-106 °C/0.05 mmHg
Density 0.939 g/mL at 25 °C
Refractive Index n20/D 1.5249
UNSPSC 12352005

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