(S)-2-(Methoxydiphenylmethyl)pyrrolidine

ALDRICH/670197 - 95% (HPLC)

CAS Number: 118971-03-2
Empirical Formula (Hill Notation): C₁₈H₂₁NO
Molecular Weight: 267.37
MDL Number: MFCD09750440
Linear Formula: C₁₈H₂₁NO
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-670197-100MG	100 mg	$342.00 1/EA		Add To Favorites
45-670197-500MG	500 mg	$846.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	95% (HPLC)
functional group	ether
	phenyl
InChI	1S/C18H21NO/c1-20-18(17-13-8-14-19-17,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17,19H,8,13-14H2,1H3/t17-/m0/s1
InChI key	CGUGCZSRPDCLBT-KRWDZBQOSA-N
optical purity	ee: ≥99.5% (HPLC)
Quality Level	200
SMILES string	COC([C@@H]1CCCN1)(c2ccccc2)c3ccccc3
storage temp.	2-8°C

Application:	(S)-2-(Methoxydiphenylmethyl)pyrrolidine is a diphenylprolinol methyl ether, which can be used as a catalyst to synthesize: • Enantioselective ketones via intermolecular asymmetric Michael addition of aldehydes to nonactivated enones. • Stereoselective chiral bipyrazolidin-3-one derivatives by dipolar cycloaddition reaction of azomethine imines with α, β-unsaturated aldehydes. • Enantioenriched spiro nitrogen heterocycles via asymmetric nucleophilic epoxidation of α-ylideneoxindole esters. • Optically active secondary alcohols by asymmetric addition of Et₂Zn to various aldehydes.
Packaging:	100, 500 mg in glass bottle
Packaging:	Bottomless glass bottle. Contents are inside inserted fused cone.

Symbol	GHS07
Signal word	Warning
Hazard statements	H302
Hazard Codes	Xn
Risk Statements	22
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	95% (HPLC)
Storage Temp.	2-8°C
UNSPSC	12352005

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