Synonym: 1,2-Bis[(2R,5R)-2,5-dimethyl-phospholanyl]3,3,4,4-tetrafluoro-1-cyclobutene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; catASium® MQF(R)Rh
CAS Number: 910048-20-3
Empirical Formula (Hill Notation): C24H36BF8P2Rh
Molecular Weight: 652.19
MDL Number: MFCD10567388
Linear Formula: C24H36BF8P2Rh
Product Type: Chemical
| assay |
≥95% (31P-NMR) |
| |
95% |
| InChI |
1S/C16H24F4P2.C8H12.BF4.Rh/c1-9-5-6-10(2)21(9)13-14(16(19,20)15(13,17)18)22-11(3)7-8-12(22)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-12H,5-8H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t9-,10-,11-,12-;;;/m1.../s1 |
| InChI key |
FAEFUBUMCYELNL-HEEUKTGESA-N |
| SMILES string |
[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C[C@@H]2CC[C@@H](C)P2C3=C(P4[C@H](C)CC[C@H]4C)C(F)(F)C3(F)F |
| Application: |
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]-3,3,4,4-tetrafluoro-1-cyclobutene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can be used as a catalyst in the hydrogenation of unsaturated lactate precursors and α-(hydroxymethyl)- acrylate derivatives. |
| Application: |
Essential Elements for Asymmetric Hydrogenations  |
| General description: |
sold in collaboration with Solvias AG |
| Legal Information: |
catASium is a registered trademark of Umicore AG & Co. KG |
| Packaging: |
500 mg in glass bottle |
| Packaging: |
Bottomless glass bottle. Contents are inside inserted fused cone. |
| RIDADR |
NONH for all modes of transport |
| Flash Point(F) |
Not applicable |
| Flash Point(C) |
Not applicable |
| Purity |
≥95% (31P-NMR); 95% |
| UNSPSC |
12352005 |
